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Aromaticity via cyclopropyl conjugation. Electronic structure of spiro[2.4]hepta-4,6-diene

✍ Scribed by Clark, Robert A.; Fiato, R. A.

Book ID: 126925104
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 342 KB
Volume: 92
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00718a047

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Although 1,2 hydrogen mlgratlon in ground state radicals are Infrequent, there are several photochemical examples2s3 In which the excited states are presumed to have "diradlcal" character. One of the flrst examples, reported by Schuster and Polowczyk,' was the photolsomerlzatlon of splrodlenone & to