Aromaticity and electronic delocalization in all-metal clusters with single, double, and triple aromatic character

Evidence for a single electron transfer

Evidence for a single electron transfer mechanism in 1he reduction of aromatic nitrogen heterocycles with main group metal hydrides and dihydropyridyl metal complexes.

✍ E.C. Ashby; A.B. Goel 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 239 KB

Direct spectroscopic (EPR) evidence is presented to support a single electron transfer mechanism to describe the reactions of various simple and complex hydrides of the main group elements and dihydropyridyl metal complexes with aromatic nitrogen heterocyclic compounds.