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Aromatic vs Diradical Character in the Transition States of the Cope Rearrangements of 1,5-Hexadiene and Its Cyano Derivatives

✍ Scribed by Blavins, Joshua J.; Cooper, David L.; Karadakov, Peter B.

Book ID: 127393887
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 264 KB
Volume: 108
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp036660i

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## Abstract A novel interpretation of the chameleonic and centauric models for the Cope rearrangements of 1,5‐hexadiene (A) and different cyano derivatives (B: 2,5‐dicyano, C: 1,3,4,6‐tetracyano, and D: 1,3,5‐tricyano) is presented by using the topological analysis of the electron localization func