Aromatic sulphonation I sulphonation of benzene and toluene in aqueous sulphuric acid: (Preliminary communication)
β Scribed by H. Cerfontain; A. W. Kaandorp; F. L. J. Sixma
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 92 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0165-0513
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π SIMILAR VOLUMES
## Abstract The isomer distribution in the homogeneous monosulphonation of toluene in 77.6β98.8 wtβ % aqueous sulphuric acid has been determined at various temperatures between 5 and 65Β°. Sulphone formation and disulphonation are negligible. The isomer distribution is independent of toluene convers
## Abstract The ratio of the overall rate constants for the sulphonation of toluene and benzene in aqueous sulphuric acid at 25Β° decreases from 110 to 25 on varying the acid concentration from 78 to 92 wtβ%. Similar trends are observed at 5Β° and 45Β°. The partial rate factors for __orthoβ, metaβ__
## Abstract Rate measurements have been made on the homogeneous sulphonation of toluene in aqueous sulphuric acid varying from 70.0 to 95.9 wtβ% at 5.0Β°, 25.0Β° and 45.0Β°. In addition, rate constants have been determined for the homogeneous sulphonation of ethylbenzene and isopropylbenzene at 25.0Β°
## Abstract The kinetics of the sulphonation of benzenesulphonic acid and __m__βtoluenesulphonic acid have been measured in oleum, containing 0.7 to 43.6% of sulphur trioxide The composition of oleum solutions is expressed in the percentage by weight of sulphur trioxide, present in excess of the co