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Aromatic substitution of olefin. IV Reaction with palladium metal and silver acetate

✍ Scribed by Yuzo Fujiwara; Ichiro Moritani; Masaoki Matsuda; Shiichiro Teranishi

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 157 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)99121-x

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✦ Synopsis

In previous papers, 1) we reported a novel substitution reaction between styrene and benzene derivatives in the presense of palladium(I1) salts such as palladium(I1) acetate, giving stilbene derivatives by substitution of aromatic compounds for hydrogen on the double bond of styrene. This is a convenient new method for the introduction of phenyl groups into the olefinic C-atom.

In this reaction, however, an equal amount of palladium(I1) salts to olefin is necessary and the palladium(I1) salt is reduced to metal in the course of this reaction. Therefore it is of interest to investigate whether palladium(I1) salts can act catalytically in this substitution reaction.

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