Aromatic ring synthesis by N-aminopyrrole Diels-Alder reaction. Characterization of the heteroatom fragment
β Scribed by Arthur G. Schultz; Ming Shen; Ramanathan Ravichandran
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 228 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Aminonitrenes are produced on reaction of x-aminopyrroles with dimethyl acetylenedicarboxylate; a new reaction of dialkyl aminonitrenes is described.
Recently, we reported the utilization of N-aminopyrroles in a Die&-Alder based substi-_ tuted benzene ring synthesis; Q., 1-f 2 + 2.
π SIMILAR VOLUMES
## Abstract Semiempirical and density functional theory computational studies were carried out with the target determining the reactivity of five membered heterocycles with heteroatoms in the 1 and 3 positions as dienes for DielsβAlder reactions. The relative reactivity was evaluated in their react