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Aromatic ring synthesis by N-aminopyrrole Diels-Alder reaction. Characterization of the heteroatom fragment

✍ Scribed by Arthur G. Schultz; Ming Shen; Ramanathan Ravichandran


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
228 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis


Aminonitrenes are produced on reaction of x-aminopyrroles with dimethyl acetylenedicarboxylate; a new reaction of dialkyl aminonitrenes is described.

Recently, we reported the utilization of N-aminopyrroles in a Die&-Alder based substi-_ tuted benzene ring synthesis; Q., 1-f 2 + 2.


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Computational investigation of the suita
✍ Branko S. Jursic πŸ“‚ Article πŸ“… 1998 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 426 KB

## Abstract Semiempirical and density functional theory computational studies were carried out with the target determining the reactivity of five membered heterocycles with heteroatoms in the 1 and 3 positions as dienes for Diels‐Alder reactions. The relative reactivity was evaluated in their react