Aromatic pathways in thieno-bridged porphyrins: understanding the influence of the direction of the thiophene ring on the aromatic character
✍ Scribed by Fliegl, Heike; Özcan, Nergiz; Mera-Adasme, Raul; Pichierri, Fabio; Jusélius, Jonas; Sundholm, Dage
- Book ID
- 120302324
- Publisher
- Taylor and Francis Group
- Year
- 2013
- Tongue
- English
- Weight
- 474 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0026-8976
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The l-and 2-CHz+ derivatives are studied in terms of variation of the C-C exocyclic bond and the torsion around it in order to show the stractural consequences in naphthalene moiety. It results that rotation around and elongation of this bond lead to the fluctuation of the electronic charge at atoms
Aromatic side chains on amino acids influence the fragmentations of cationic complexes of doubly charged metal ions and singly deprotonated peptides. The metal ion interacts with an aromatic side chain and binds to adjacent amide nitrogens. When fragmentation occurs, this bonding leads to the format