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Aromatic nucleophilic substitution of hydrogen: mechanism of reaction of 6-nitroquinoline with cyanide ions, with and without participation of methyl cyanoacetate

✍ Scribed by Halama, Aleš; Kaválek, Jaromír; Macháček, Vladimír; Weidlich, Tomáš

Book ID
118050279
Publisher
Royal Society of Chemistry
Year
1999
Weight
280 KB
Volume
13
Category
Article
ISSN
1472-7781

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✍ Yao-Jun Shi; Guy Humphrey; Peter E. Maligres; Robert A. Reamer; J. Michael Willi 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 78 KB

## Abstract Exclusive formation of 6‐aryloxy ethers **9** from an S~N~Ar reaction of methyl 2,6‐dichloronicotinate (**2**) with phenols **7** catalyzed by 1,4‐diazabicyclo[2.2.2]octane (DABCO) in the presence of stoichiometric triethylamine is described. The reaction proceeds __via__ the regioselec