Aromatic hydrogen isotope effects in reactions of benzenediazonium salts
β Scribed by Swain, C. Gardner; Sheats, John E.; Gorenstein, David G.; Harbison, Kenneth G.
- Book ID
- 126009002
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 657 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The observation that aromatio halogenation with moleoular halogen ie a lees eeleotive reaotion with polymetbylbeneenee then with monosubatituted benzenee, a~ based on the reaotion con&ante of the reaotione in eaoh individual eerie6 2,3 , aaggests that the two methyl group8 ortho to the attaoked posi
The PODSs of the Hs system and its isotopic derivatives are used for computing exact adiabatic barriers we Fmd good agreement with experimentally measured ground and vibrationally excited activation energies. The theoretical results should stimulate further measurements of activation energies of vib