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Aromatic H/D Exchange Reaction Catalyzed by Groups 5 and 6 Metal Chlorides.

โœ Scribed by Qiao-Xia Guo; Bao-Jian Shen; Hai-Qing Guo; Tamotsu Takahashi

Publisher
John Wiley and Sons
Year
2005
Weight
24 KB
Volume
36
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

๐Ÿ“œ SIMILAR VOLUMES

Aromatic H/D Exchange Reaction Catalyzed
Aromatic H/D Exchange Reaction Catalyzed by Groups 5 and 6 Metal Chlorides
โœ Guo Qiao-Xia; Shen Bao-Jian; Guo Hai-Qing; Takahashi Tamotsu ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 68 KB

Groups 5 and 6 metal chlorides such as MoCl 5 , WCl 6 , NbCl 5 and TaCl 5 were found to be simple and very efficient catalysts for the aromatic H/D exchange reactions. Compared with other metal chlorides such as ZnCl 2 , SnCl 4 and TiCl 4 , groups 5 and 6 metal chlorides showed better catalytic acti

On the electronic structure and bonding
On the electronic structure and bonding of the polynuclear aryl derivatives of the group IB metals Cu5(C6H5)5, Ag4(C6H5)4 and Au5(C6H5)5 by density functional theory
โœ Paola Belanzoni; Marzio Rosi; Antonio Sgamellotti; Evert Jan Baerends; Carlo Flo ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 608 KB

Density functional calculations are carried out on the Cu5(C6Hs)5, Ag4(C6Hs)4 and Aus(CrHs)5 systems. Electronic structure and bonding aspects of the interaction between the Mn and (C6H5)n units are investigated. Calculations are performed on the corresponding naked clusters of four and five metal a