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Aromatic enynes as substrates for the intramolecular Pauson-Khand reaction

✍ Scribed by Jaime Blanco-Urgoiti; Luis Casarrubios; Javier Pérez-Castells


Book ID
104261062
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
228 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis


Pauson-Khand reactions are carried out with different substituted aromatic enynes yielding tricyclic cyclopentenones related to natural products. Reaction is promoted by dissolved Me3NO. Isomedzation of the double bond of the cyclopentenone is observed except for compound 2e, with a non terminal triple bond.


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ChemInform Abstract: Intramolecular Paus
✍ Carl J. Lovely; Hemalatha Seshadri 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

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