Aromatic enynes as substrates for the intramolecular Pauson-Khand reaction
✍ Scribed by Jaime Blanco-Urgoiti; Luis Casarrubios; Javier Pérez-Castells
- Book ID
- 104261062
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 228 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Pauson-Khand reactions are carried out with different substituted aromatic enynes yielding tricyclic cyclopentenones related to natural products. Reaction is promoted by dissolved Me3NO. Isomedzation of the double bond of the cyclopentenone is observed except for compound 2e, with a non terminal triple bond.
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