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Aromatic Dienophiles. 1. A Theoretical Study of an Inverse-Electron Demand Diels−Alder Reaction between 2-Aminopyrrole and 1,3,5-Triazine

✍ Scribed by Yu, Zhi-Xiang; Dang, Qun; Wu, Yun-Dong


Book ID
126963336
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
145 KB
Volume
66
Category
Article
ISSN
0022-3263

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The scope of 1,3,5-triazine inverse electron-demand Diels-Alder (IDA) reactions was expanded to include aminothiophenecarboxylic acids as latent dienophiles. A series of 2-amino-3-thiophenecarboxylic acids (1a-d) and a 3-amino-2-thiophenecarboxylic acid (5) were introduced as productive dienophiles