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Aromatic cyclodehydration of 2-benzylphenyl and 2-(1-naphthylmethyl)phenyl benzo[b]thienyl ketones

✍ Scribed by Henson, Paul D.; Vingiello, Frank A.


Book ID
126429088
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
413 KB
Volume
32
Category
Article
ISSN
0022-3263

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N-(3-Benzo[b]thienyl)iminophosphoranes t
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The novel N- (3-benzo[b]thienyl)iminophosphoranes 1b-d react with a,b-unsaturated aldehydes and ketones 2a-e to give varying mixtures of the regioisomeric benzothieno[3,2-b]pyridines 3a-d and 4a-d as a result of preferential attack of either imino nitrogen or a-thienyl carbon at the enone carbonyl g