Aromatic biotransformations 2: production of novel chiral fluorinated 3,5-cyclohexadiene-cis-1,2-diol-1-carboxylates
β Scribed by John T. Rossiter; Steve R. Williams; Anthony E.G. Cass; Douglas W. Ribbons
- Book ID
- 104227318
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 125 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
A novel C~-symmetric bis-sulfoxide 1 was synthesized as a chiral auxiliary for asymmetric desymmetrization of meso-1,2-diols. cis-Cyclohexane-1,2-dioi and cis-cyclopentane-1,2-diol were desymmetrized via acetalization with I followed by basepromoted acetal cleavage with high diastereoselectivity (>9
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