Aristomakine, a novel indole alkaloid from aristotelia serrata
โ Scribed by I.Ralph C. Bick; Mohammad A. Hai
- Book ID
- 104234215
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 128 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The isolation and structural determination of aristomakine (I), an unusual indole alkaloid with an N-isopropyl group, is reported. Indole alkaloids from Aristotelia spp. l-10 are distinguished by the incorporation into their structures of a monoterpene unit which has not undergone previous rearrangement to loganin, although considerable subsequent rearrangement may take place. Aristomakine,
๐ SIMILAR VOLUMES
Aristotelinone and serratoline, two new Aristotetia alkaloids, are shown to have indole and indolenine structures respectively from their spectra and reduction products. The structure and absolute configuration of aristoteline (I), the main alkaloid of the New Zealand plant A. sepruta (and of the So