Arenediazonium o-Benzenedisulfonimides: Some Kinetics of Azo Coupling Reactions with Naphthols
✍ Scribed by Carla Boga; Jacopo Degani; Erminia Del Vecchio; Rita Fochi; Luciano Forlani; Paolo E. Todesco
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 116 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-193X
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✦ Synopsis
Kinetic investigation of azo coupling reactions between naphthols and 4-methoxy-and 4-nitrobenzenediazonium obenzenedisulfonimides has been carried out for comparison with the related benzenediazonium tetrafluoroborates. The data clearly indicate that the two kinds of diazonium salts show very similar reactivities. This fact emphasizes that arenediazonium o-benzenedisulfonimides, which are very stable, may be used as alternatives to the more usual diazonium salts. The azo coupling reactions between 4-nitro-
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## Abstract The reaction between various arenediazonium __o__‐benzenedisulfonimides and triorganoindium compounds is described. Depending on the reaction conditions, it is possible to obtain biaryls (16 examples, average yield of 79 %) or diaryldiazenes (18 examples, average yield of 81 %). __o__‐B
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Preparation of Diazenes by Electrophilic C-Coupling Reactions of Dry Arenediazonium o-Benzenedisulfonimides with Grignard Reagents. -Twenty-three different aryldiazenes (III) are prepared by electrophilic C-coupling reactions of highly pure and stable salts (I) with Grignard reagents. Work-up temp.