𝔖 Bobbio Scriptorium
✦   LIBER   ✦

(Arene)Cr(CO)3 Complexes: Aromatic Nucleophilic Substitution

✍ Scribed by Martin F. Semmelhack; Anatoly Chlenov

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Hydrogen bonding networks in [(Ξ·6-arene)
Hydrogen bonding networks in [(Ξ·6-arene)Cr(CO)3] complexes
✍ Balasubramanian Murugesapandian; Peter W. Roesky πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 293 KB πŸ‘ 1 views

The four different [(Ξ· 6 -arene) and [{Ξ· 6 -(1,4-C 6 H 4 (NH 2 )CH 3 )}Cr(CO) 3 ] were synthesized and structurally characterized by single crystal X-ray diffraction. All compounds form hydrogen bonds in the solid state, leading to dimeric or polymeric networks. The hydrogen bonds are an essential

Modern Arene Chemistry || Arenetricarbon
Modern Arene Chemistry || Arenetricarbonylchromium Complexes:Ipso,Cine,Tele Nucleophilic Aromatic Substitutions
✍ Astruc, Didier πŸ“‚ Article πŸ“… 2002 πŸ› Wiley-VCH Verlag GmbH & Co. KGaA βš– 375 KB πŸ‘ 1 views

The complexation of an arene C 6 H 5 X to the tricarbonylchromium unit promotes addition of nucleophiles to the arene ring due to the strong electron-withdrawing ability of the Cr(CO) 3 group. If addition of the nucleophile Nu occurs at the carbon bearing the leaving group X, this is an overall ipso