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Arene derivatives of zirconium(II) and hafnium(II)

โœ Scribed by Calderazzo, Fausto; Pallavicini, Piersandro; Pampaloni, Guido

Book ID
121261711
Publisher
The Royal Society of Chemistry
Year
1990
Tongue
English
Weight
798 KB
Volume
6
Category
Article
ISSN
1472-7773

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Zirconium(II)- and Hafnium(II)-Assisted
Zirconium(II)- and Hafnium(II)-Assisted Reductive Coupling of Coordinated Carbonyl Groups Leading to Ketenylidene Complexes of Zirconium(IV) and Hafnium(IV)
โœ Prof. Dr. Fausto Calderazzo; Dr. Ulli Englert; Dr. Alessandro Guarini; Dr. Fabio ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 1004 KB

The biscyclopentadienyldicar-bony1 derivatives of zirconium(i1) and hafnium(r1) ([MCp,(CO),]; M = Zr, Hf) promote the reductive coupling of coordinated carbon monoxide to give, in the presence of N,N-dialkylcarbamates of the tetravalent metals (M(02CNR2),]. the ketenylidene complexes [M,Cpz(p2-CCO)-