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Are There Hydrogen Bonds in Supercritical Water?

✍ Scribed by Hoffmann, Markus M.; Conradi, Mark S.

Book ID
121242926
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
276 KB
Volume
119
Category
Article
ISSN
0002-7863

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A detailed analysis of hydrogen bonding in supercritical water is made from Monte Carlo simulations along the 773 K isotherm over a wide range of pressures from 10 to 10000 MPa. It is shown that an energetic definition of H-bonding is much more effective in separating H-bonded and non-bonded molecul