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Aqueous solvation effect on the tautomerism of 8-azapurine

✍ Scribed by J.Guillermo Contreras; Sandra T. Madariaga; Joel B. Alderete

Book ID
113258977
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
593 KB
Volume
365
Category
Article
ISSN
0166-1280

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Solvation effects on the tautomerization
Solvation effects on the tautomerization of N,N-dimethylvaline
✍ Allan D. Headley; Binita Patel; Eric T. Cheung πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 185 KB

The effects that solvents have on the tautomerization of N,N-dimethylvaline were analyzed using a linear solvation energy relationship (LSER) approach. In solution, the population of the zwitterionic tautomer is dictated mainly by the nature of the medium. Acidic solvent molecules appear to be more