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Aqua­(benzene-1,3-dioxy­acetato-κO)­tetrakis(1H-imidazole-κN3)­nickel(II) monohydrate

✍ Scribed by Gao, Shan ;Liu, Ji-Wei ;Huo, Li-Hua ;Zhao, Hui ;Zhao, Jing-Gui


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
335 KB
Volume
60
Category
Article
ISSN
1600-5368

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catena-Poly­[[aqua­bis(1H-imidazole-κN3)
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.054 wR factor = 0.109 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.029 wR factor = 0.071 Data-to-parameter ratio = 16.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title mononuclear nickel(II) complex, [Ni(C 3 H 4 N 2 ) 4 ]-(NO 3 ) 2 , the Ni II atom is four-coordinated in a square-planar geometry by four N atoms from four imidazole ligands. The nitrate anions are linked to the nickel(II) complex cations through intermolecular N-HÁ Á ÁO hydrogen bonds.