Aqua[4-bromo-2-(pyridin-2-ylmethyliminomethyl)phenolato]copper(II) nitrate monohydrate
✍ Scribed by Sun, Yu-Xi ;Gao, Gen-Zhi ;Pei, Hong-Xia ;Zhang, Rui
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 276 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê Disorder in solvent or counterion R factor = 0.041 wR factor = 0.103 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Mn(C 13 H 10 BrN 2 O) 2 ]NO 3 , consists of a mononuclear manganese(III) complex cation and a nitrate anion. In the cation, the Mn III atom is coordinated by four N atoms and two O atoms from two tridentate Schiff base ligands, forming an octahedral complex.
In the cation of the title complex, [Zn(C 13 H 10 BrN 2 O)(H 2 O)]-(NO 3 )ÁH 2 O, the Zn atom is coordinated by two N and two O atoms, giving a slightly distorted square-planar geometry. The crystal structure is stabilized by intermolecular O-HÁ Á ÁO hydrogen-bond interactions.