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Aqua­[4-bromo-2-(pyridin-2-ylmethylimino­methyl)phenolato]copper(II) nitrate monohydrate

✍ Scribed by Sun, Yu-Xi ;Gao, Gen-Zhi ;Pei, Hong-Xia ;Zhang, Rui


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
276 KB
Volume
61
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES


[4-Bromo-2-(pyridin-2-ylmethyl­imino­met
✍ Sun, Yu-Xi 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 276 KB

Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê Disorder in solvent or counterion R factor = 0.041 wR factor = 0.103 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis[4-bromo-2-(pyridin-2-ylmethyl­imino­
✍ Wang, Nong 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 239 KB

The title compound, [Mn(C 13 H 10 BrN 2 O) 2 ]NO 3 , consists of a mononuclear manganese(III) complex cation and a nitrate anion. In the cation, the Mn III atom is coordinated by four N atoms and two O atoms from two tridentate Schiff base ligands, forming an octahedral complex.

Aqua­[4-bromo-2-(pyridinylmethyl­imino­m
✍ Chen, Yue 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 261 KB

In the cation of the title complex, [Zn(C 13 H 10 BrN 2 O)(H 2 O)]-(NO 3 )ÁH 2 O, the Zn atom is coordinated by two N and two O atoms, giving a slightly distorted square-planar geometry. The crystal structure is stabilized by intermolecular O-HÁ Á ÁO hydrogen-bond interactions.