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Aqua(2-chloronicotinato)triphenyltin(IV)

✍ Scribed by Xu, Hao-Long ;Yin, Han-Dong ;Li, Gang

Book ID: 104486705
Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 94 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680600626x

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✦ Synopsis

The title complex, [Sn(C~6~H~5~)~3~(C~6~H~3~ClNO~2~)(H~2~O)], is five-coordinate with a distorted trigonal–bipyramidal geometry in the solid state. The O atom of the carboxylate group occupies one of the axial sites and the O atom of the water molecule occupies the other. Water H atoms are involved in an intermolecular hydrogen-bonded network with the uncoordinated carboxylate O atom and the pyridine N atom; the interactions lead to two types of rings.

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✦ Synopsis

Aqua(2-chloronicotinato)triphenyltin(IV)