This "relativistic contraction" is here found to be 0.64, where part of this work was done. 2.3 and 5.6 per cent for GeH,, SnH4 and P'oH4, respectively. This effect can be interpreted by the known fact that the s and p1j2 shells shrink [I, 161 due to re-References lativity. Orthogonality constraints
✦ LIBER ✦
Approximate Relativistic calculations within the one-center approximation for the series CH4 TO PbH4
✍ Scribed by A. Aguilar-Ancono; J.L. Gázquez; J. Keller
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 316 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
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✍
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📂
Article
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1974
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🌐
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⚖ 640 KB
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✍
G.C. Tabisz
📂
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📅
1977
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🌐
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⚖ 356 KB
Calculation of the excited states of H2S
✍
Yasuyo Hatano
📂
Article
📅
1978
🏛
Elsevier Science
🌐
English
⚖ 300 KB
Excitation energies are calculated for the states arising from excitation of an outer-most valence electron of HzS, PH3 and S& by the use of the one-center expansion SCF MO and the improved virtual orbital approximations. The results are compared with experimental data.