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Approximate Rate Constants for Cyclizations of Alkyl Radicals onto Benzyl Oxime Ethers

โœ Scribed by Sunggak Kim; Yeonjoon Kim; Kwang Sup Yoon


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
477 KB
Volume
38
Category
Article
ISSN
0040-4039

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Reactions of sodium naphthalenide with alkyl chlorides, bromides, and iodides produce free alkyl radicals which subsequently react with sodium naphthalenide, generating alkylsodiums through electron-transfer and alkylated naphthalenides through radical combination (l-7). 5-Hexenyl halides have playe