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Approaches to the total synthesis of phomactins

✍ Scribed by Andrew S Balnaves; Graham McGowan; Peter D.P Shapland; Eric J Thomas

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 272 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00341-1

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✦ Synopsis

The macrocyclic triene 34, an advanced intermediate for synthesis of phomactins, has been synthesized using the 2,3-Wittig rearrangement of the propargylic ether 21 as a key step.

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