Rccenrd 17 Oxobcr 1980 4n approwmate electron propngaror method for prcdlcrne calcukirwns of molccuiar electron ctffuntles IS proposed The self-encrgi 3ccounts for rehiatlon effects to all orders .Addltlon;ll correhtlon effects are treated usmg a diagonal approxunatlon \\lth shdted denommators Apphu
Applying electron propagator theory to electron affinities
โ Scribed by J. V. Ortiz
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 318 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Simons and Smith have alculated electron affiities znd ionization poter?tizls through third order in the elec;ronic interaction by invokhg th: equations of motion method. An alternative analysis of the order is offered here by espanding the decominztoi in their :,>seudoeigenvalue eqation to generate
The vertical electron detachment energy of Cc and the adiabatic electron affinity of Cs are calculated with ab initio electron propagator methods. The former energy difference is 2.86 eV and the latter is 2.82 eV. These values are in close agreement with recent experimental determinations. Structura