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Applications of Raman magnetic resonance to heteronuclear spin systems

✍ Scribed by Daiwen Yang; Chaohui Ye

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
590 KB
Volume
31
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Raman magnetic resonance (RMR) with direct and indirect detection schemes features 1D display of multiple quantum (MQ) transitions. Consequently, useful information such as couplings and correlations can be easily extracted from the RMR approach. In this paper, RMR experiments are demonstrated to determine heteronuclear chemical shift correlations, homonuclear and heteronuclear long‐range coupling constant values and their relative signs, with typical samples. It is shown that this approach is useful for the study of small molecules and groups of special interest in a complex molecule.

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