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Applications of molybdenum-95 NMR. 8. Molybdenum(0) carbonyl derivatives of phosphines, phosphites and related ligands

✍ Scribed by Masters, Anthony F.; Bosbard, Gerald E.; George, T. Adrian; Brownlee, Robert T. C.; O'Connor, Maxwell J.; Wedd, Anthony G.


Book ID
125935142
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
486 KB
Volume
22
Category
Article
ISSN
0020-1669

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Applications of 95Mo NMR. 5β€”substituent
✍ R. T. C. Brownlee; A. F. Masters; M. J. O'Connor; A. G. Wedd; H. A. Kimlin; J. D πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 496 KB

A systematic study has been made of the effects of substituent induced chemical shifts in [($-C,H,)(CO),Mo(CH,Cd€,R)] compounds. Both 9sM0 and "C NMR shifts in the aromatic ring are reported. The (q'-C5H,)(CO)&loCH2-group is a reasonably strong resonance donor (aR0=-0.21) and weak inductive donor (