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Applications of chiral sulfoxides in enantioselective synthesis of diols and total synthesis of natural products

✍ Scribed by Guy Solladie

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
228 KB
Volume
13
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The sulfoxide mediated enantioselective reduction of carbonyl compounds was extended to the synthesis of enantiomerically pure syn and anti diols, including C~2~ symmetric diols. Several applications related to the syntheses of natural products are described. Finally, this sulfoxide mediated enantioselective synthesis was extended to the transformation of ethyl oxalate or other oxalic acid derivatives to enantiomerically pure syn and anti 1,2‐diols. Β© 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:443–452, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10079

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