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Applications of Aziridinium Ions. Selective Syntheses of α,β-Diamino Esters, α-Sulfanyl-β-amino Esters, β-Lactams, and 1,5-Benzodiazepin-2-one

✍ Scribed by Chuang, Tsung-Hsun; Sharpless, K. Barry

Book ID
121693350
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
54 KB
Volume
2
Category
Article
ISSN
1523-7060

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✍ Fred H van der Steen; Johann T.B.H Jastrzebski; Gerard van Koten 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 262 KB

A new one-pot synthesis of 3-amino-g-lactams that is based on the condensation of simple imines with zinc enolates of disilyl protected glycine esters is mported Isolated yields are high and a rranr-selectivity is observed. ## with imines. With N-(benzylidene)-trimethylsilylamine the ring-closure