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Applications of 95Mo NMR spectroscopy. XV. 95Mo NMR parameters for [Mo(CO)6−n (pyridine)n] (n = 1−3) complexes. A reassignment of the fac-[Mo(CO)3(pyridine)3] resonance

✍ Scribed by Robert T.C Brownlee; Maxwell J O'Connor; B.Philip Shehan; Anthony G Wedd

Publisher
Elsevier Science
Year
1985
Weight
177 KB
Volume
64
Category
Article
ISSN
0022-2364

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Poor correlations are normally observed between the chemical shifts of the various NMR-active nuclei in Mo carbonyl complexes of group 15 ligands as the group 15 atom substituents are varied. It is possible to observe good chemical shift correlations and to develop relationships between chemical shi