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Application on novel fragmentation reaction: A concise synthesis of 2,3,5-trisubstituted furans from butenolides

✍ Scribed by Xuqing Zhang; Elieen U. Jackson; Arthur G. Schultz


Publisher
Journal of Heterocyclic Chemistry
Year
2006
Tongue
English
Weight
100 KB
Volume
43
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

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Butenolides 4, generated from a novel fragmentation reaction, function as excellent precursors to 2,3,5‐trisubstituted furans 5 by additions of alkyl or aryl metallic reagents. It can also be converted into siloxyfurans 6 by treatment with silylating reagents.


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