Three bond proton-proton vicinal coupling constants are of postripe-COSY requires significantly shorter total experimental tential value for analyzing sugar conformations in DNA. However, time than a standard COSY-35 spectrum. In the example self-cancellation in antiphase cross peaks and modulation
โฆ LIBER โฆ
Application of the z-COSY technique with a modified pulse sequence to measurement of coupling constants in macromolecules
โ Scribed by Hartmut Oschkinat; G Marius Clore; Michael Nilges; Angela M Gronenborn
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 369 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0022-2364
No coin nor oath required. For personal study only.
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We propose a new method for the determination of the quadrupolar coupling constant e'qQ/h of a spin I= 3/2 in powdered samples. It is suitable for characterizing a nucleus with a featureless central transition line shape where it is difkult to extract the value of e\*qQ/h from the spectrum. The puls