## Abstract As the result of the crystallization of copper sulfate from waste liquor using commercial scale plant, it became clear that the application of the thermal history of solution was very effective to depress nucleation as expected previously. The optimum setup of crystallizer to recover c
Application of the thermal history of copper sulfate solution to industrial crystallization (I). Crystallization with pilot plant
โ Scribed by Dr. T. Nakai; Y. Aoyama; K. Miyake
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 530 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0232-1300
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โฆ Synopsis
Abstract
The relationship between the thermal history and the waiting time in nucleation decided for the aqueous solution of sodium chlorate was verified for the aqueous solution of copper sulfate using pilot crystallizers. The following items were clarified as the result of the experiments.
The cooling method is more stable to nucleation in comparison with the vacuum cooling method even at the same operational conditions.
The desirable effect of the thermal history is recognized only in the case in which the solution is heated up to a high degree of undersaturation.
The residence time at an undersaturated state has an important role to dissociate embryos in solution.
๐ SIMILAR VOLUMES
Poly( 2vinylpyridine) or poly(4-vinylpyridine) coated on a piezoelectric quartz crystal adsorbed copper, thus decreasing the oscillation frequency. The bound copper could be removed by EDTA solution. Poly( 4-vinylpyridine) is recommended to determine copper (5-35 MM) in a maleate buffer at pH 6.6 fl