Incorporation of deuterium into the enobzable positions of several cyclic and bicyclic ketones alters the magnetic field dependence of CIDNP resulting from photolysis of the ketones. These results cannot be explained in terms of D-induced changes in the conformational populations of the biradicals f
Application of the semiclassical description of hyperfine interaction to studies of the dependence of the CIDNP effect on an external magnetic field
โ Scribed by N.E. Polyakov; P.A. Purtov; T.V. Leshina; M.B. Taraban; R.Z. Sagdeev; K.M. Salikhov
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 404 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The semiclassical description of hypertine interactions has been applied to the computation of the net CIDNP effect in multinuclear radical pairs in weak magnetic fields. The method proposed was used for the investigation of the mutual effect of nuclei on CIDNP formation in various magnetic fields. The calculated field dependences have been compared with experiment.
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