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Application of the method CORDAL based on the combination of the convolution molecule method and the residual analysis to the structure determination of 3-dehydro gibberellin A3

✍ Scribed by Dr. L. Kutschabsky; Dr. G. Reck; Dr. S. Kulpe; Dr. E. Höhne

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
502 KB
Volume
10
Category
Article
ISSN
0232-1300

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✦ Synopsis

Abstract

In connection with studies of the solid state photolysis the crystal and molecular structure of 3‐dehydro gibberellin A~3~ was determined by X‐ray analysis. The final discrepancy factor R was 0.078. The packing of the molecules in the crystal explains the preference of intramolecular photoaromatization in contrast to the topophotodimerisation of the corresponding methylester upon UV‐irradiation. In this structure determination the method CORDAL, based on the combination of the convolution molecule method by Hoppe and Paulus and the residual analysis, was applied successfully.

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