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Application of the Intramolecular Yamamoto Vinylogous Aldol Reaction to the Synthesis of Macrolides

โœ Scribed by Abramite, Joseph A.; Sammakia, Tarek

Book ID
126043255
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
119 KB
Volume
9
Category
Article
ISSN
1523-7060

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Advances in the vinylogous Mukaiyama ald
Advances in the vinylogous Mukaiyama aldol reaction and its application to the synthesis of the C1๎—ธC7 subunit of oleandolide
โœ Jorma Hassfeld; Markus Kalesse ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 106 KB

The synthesis of a stereo pentade of the macrolide antibiotic oleandolide is reported. The C1 C7 fragment resembles the analogous segment of Panek's total synthesis of oleandolide. The use of the vinylogous Mukaiyama aldol reaction shortens the route significantly and has the advantage of utilizing