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Application of the indo molecular orbital method to ortho effects in mass spectra. Cleavage of cis-β-methoxystyrene

✍ Scribed by Jar-Lin Kao; Carol E. Parker; Maurice M. Bursey


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
380 KB
Volume
9
Category
Article
ISSN
1076-5174

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Stereochemical effects in the mass spect
✍ Károly Vékey; Árpád Somogyi; József Tarnás; Gabriella Pócsfalvi 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 636 KB

## Abstract Large differences have been found between the mass spectra of __cis__‐ and __trans__‐1‐carbomethoxy‐2‐trimethylsilylcyclopropane. To help in explaining these differences, quantum chemical calculations were performed by the MNDO method on the neutral molecules, on the vertical and adiaba