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Application of the hypervirial perturbation theory to the vibrational-rotational spectroscopy of diatomic molecules

✍ Scribed by Fernández, Francisco M.; Ogilvie, J. F.

Book ID
121079095
Publisher
The American Physical Society
Year
1990
Tongue
English
Weight
349 KB
Volume
42
Category
Article
ISSN
1050-2947

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Commutator perturbation method in the study of vibrational–rotational spectra of diatomic molecules
✍ Adelio Matamala-Vásquez; Jacek Karwowski 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 165 KB 👁 2 views

The commutator perturbation method, an algebraic version of the Van Vleck-Primas perturbation method, expressed in terms of ladder operators, has been applied to solving the eigenvalue problem of the Hamiltonian describing the vibrational-rotational motion of a diatomic molecule. The physical model