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Application of the Hammett equation in octahedral aquation of cobalt(III)-amine complexes

โœ Scribed by Lee, W. K.; Poon, C. K.

Book ID
126100671
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
362 KB
Volume
13
Category
Article
ISSN
0020-1669

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โœ D. R. Fenemor; D. A. House ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 482 KB

Aquation rates for cis-CoCl(en)2(A)2+ (A = 3,5-lutidine, imidazole, N-methylimidazole, benzimidazole) have been determined by halide release titration in 1 .O M HNOz at 50-80ยฐC. Kinetic parameters are (in the above order of A) 1O7k29s (sec-I), 7.4, 5.7, 1.3, 9.7; E, (kJ/mole), 103, 101, 130, 112; lo