## Abstract ^13^C nuclear magnetic resonance has been successfully used for the determination of the chemical structure of sulfonated ureaโformaldehyde resins. Model compounds (such as dimethylol urea and trimethylene diurea) were prepared and their NMR spectra were analyzed. The model compounds we
Application of the graph theory and 13C NMR spectroscopy to describe the configurational statistics of urea-formaldehyde resins
โ Scribed by S.V. Korolev; S.G. Alekseyeva; S.I. Kuchanov; I.Ya. Slonim; G.S. Matvelashvili; M.G. Slin'ko
- Book ID
- 116048438
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 597 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0032-3950
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Phenolโureaโformaldehyde (PUF) resins were synthesized by reacting mixture of methylolureas (MMU), phenol, and formaldehyde. The structure of PUF cocondensed resins at different stages of reaction were analyzed by liquid ^13^C nuclear magnetic resonance (NMR) spectroscopy. The liquid ^1
The experimental time of 13 C-NMR quantitative analysis of phenol-formaldehyde resins was reduced so that quantitativeness was maintained. The quantitative spectra of 14 model resins were obtained using a gated decoupling technique suppressing the NOE. The paramagnetic additive, Cr(acac) 3 , was use
## REFERENCE DATA of the alcohol into the acetate (7) and ketone (ll), respectively. The C-29 signal in 2, however, is virtually unaffected by acetylation (6), while it is appreciably shielded (3.9 ppm) on conversion to ketone 10. Similar shift behaviour was also observed for the C-29 and C-30 sig