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Application of the effective harmonic oscillator in thermodynamic perturbation theory

โœ Scribed by K.V. Ermakov; B.S. Butayev; V.P. Spiridonov

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
510 KB
Volume
144
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The coordinate probability distribution function for a one-dimensional anharmonic oscillator is derived by application of the effective harmonic oscillator (EHO) density matrix in first-order thermodynamic perturbation theory. The practical utility of this approach is demonstrated by the calculation of quantities obtainable by electron diffraction, namely the distance rs and amplitude le, and of vibrational partition functions for HZ, N, and Iz from the Morse potential.

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