Application of the Diels−Alder Reaction to Polymers Bearing Furan Moieties. 2. Diels−Alder and Retro-Diels−Alder Reactions Involving Furan Rings in Some Styrene Copolymers
✍ Scribed by Goussé, Cécile; Gandini, Alessandro; Hodge, Philip
- Book ID
- 119964807
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 490 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0024-9297
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The Diels-Alder cycloaddition between several 2-, and 3-substituted furans and E-i,2bis(phenylsulfonyl)ethylene have been carried out in high yields. Stereoselectivity observed in the case of 2-sustimted furans has been explained by means of the MM3-transition state model. The model had to be refine
Heteroatom variants of the type 2 intramolecular Diels-Alder reaction provide an efficient method for the preparation of bridged bicyclic heterocycles. The type 2 variant of the intramolecular N-acylnitroso Diels-Alder reaction is an effective method for the synthesis of bridged bicyclic oxazinolact