Application of the de Mayo reaction to the preparation of tricyclo[6.3.0.02,6]undecanes: a photochemical synthesis of (.+-.)-hirsutene
β Scribed by Disanayaka, Bimsara W.; Weedon, Alan C.
- Book ID
- 118154938
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 952 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Tricyclo[3.3.0. 02' %ctane (l) , built up from four equivalent methylene and four equivalent methine groups, is one of the most readily obtainable bicyclo[2.1. llhexane derivatives. 2 At the same time, 1 can be viewed as a small-ring analog of adamantane (2), the tricyclic Cl0 hydrocarbon built up
A novel synthesis of the tricyclo[5.3.1.0 2,6 ]undecane compound 16, basic carbon skeleton of gymnomitrane class of sesquiterpenoids, and the transformation into the bicyclo[5.3.1]undecane derivative 18, the AB carbon framework of taxol (6), have been achieved. Beginning with the bicyclo[3.2.1]octan