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Application of the carbonyl epoxide rearrangement to the formation of dioxabicycloalkanes and alkenes. Synthesis of the mus musculus pheromone.

โœ Scribed by Harry H. Wasserman; Steven Wolff; Teruo Oku

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
189 KB
Volume
27
Category
Article
ISSN
0040-4039

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Two components [2-sec-butyl-4,5-dihydrothiazole (1) and were obtained with an enantiomeric purity of ca. 92% ee and were found to be readily racemizable. Asymmetric 3,4-dehydro-exo-brevicomin (2)] of a male-produced pheromone of the mouse Mus musculus have been dihydroxylation was employed as the ke