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Application of the Canonical Flexible Transition State Theory to CH 3 , CF 3 , and CCl 3 Recombination Reactions

✍ Scribed by Pesa, Michèle; Pilling, Michael J.; Robertson, Struan H.; Wardlaw, David M.

Book ID: 127264045
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 231 KB
Volume: 102
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp981700h

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## Abstract The rate coefficient for NH~2~ + CH~4~ → NH~3~ + CH~3~ (R1) has been measured in a shock tube in the temperature range 1591–2084 K using FM spectroscopy to monitor NH~2~ radicals. The measurements are combined with a calculation of the potential energy surface and canonical transition s