Application of the anharmonic coherent states to the vibronic interaction

✍ Scribed by C.N. Avram; Gh.E. Drăgănescu

• Book ID: 105357238
• Publisher: John Wiley and Sons
• Year: 2003
• Tongue: English
• Weight: 85 KB
• Volume: 51
• Category: Article
• ISSN: 0015-8208
• DOI: 10.1002/prop.200310004

✦ Synopsis

Abstract

We calculated the vibronic reduction factor (Ham factor) for the physical system (molecules, crystals) with octahedral symmetry. The vibrations of the nuclei of the systems are described by the anharmonic states of the Morse potential and also by the anharmonic coherent states of the same potential. The linear vibronic coupling of these vibration states with the electronic states of the system are considered.