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Application of statistical experimental design in Ziegler–Natta polymerization of butadiene

✍ Scribed by F. K. W. Ho; C. C. Hsu; D. W. Bacon

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
656 KB
Volume
32
Category
Article
ISSN
0021-8995

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✦ Synopsis

The results of butadiene polymerization initiated with CoC1, . 4Py/Et,A1C1/H2O are presented. The effectiveness of statistical experimental design techniques is demonstrated in identifying the individual and joint effects of polymerization variables on rate constants, molecular weights, and polydispersity. The proposed conversion model, representing polymerization with instantaneous initiation and bimoiecular termination, was found to provide an adequate representation of experimental conversion data. Evidence indicates that water is not only directly involved in the initiation reaction but also plays an important role in the chain transfer reaction.

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