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Application of spin trapping to the detection of radical intermediates in electrochemical transformations

โœ Scribed by Bard, Allen J.; Gilbert, John C.; Goodin, Richard D.


Book ID
126825645
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
272 KB
Volume
96
Category
Article
ISSN
0002-7863

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Spin Trapping of Radical Intermediates G
โœ Petr Majzlรญk; Ladislav Omelka; Renata Superatovรก; Petra Holubcovรก ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 253 KB

## Abstract A series of substituted 4โ€methylphenols **1** and **2** was oxidized with PbO~2~ in the presence of nitroso compounds **3**โ€“**10**. The formation of adducts of benzyl radicals with the nitroso spin traps in the reaction mixture was established, suggesting the abstraction of an Hโ€atom fr